Plastic recycling | Food Packaging Forum (2023)

The steadily increasing production of plastic causes severe environmental problems, which include high energy demand during production, consumption of fossil fuels and accumulation of plastic waste in landfills and natural environments. In the context of food packaging, approaches to reduce or slow-down the demand for virgin plastic have been developed and are already applied to different extents. These strategies include the reduction of packaging weight and/or volume, the reuse of packaging, and the recycling of certain polymers (3R).

1. Recycling steps

Identification and sorting

In 1988, the Society of the Plastics Industry (SPI) devised the resin identification code (RIC) aiming at the efficient identification and separation of different plastics (Table 1). In 2013, ASTM International issued the replacement of the three “chasing arrows”, which are often associated with recycling, by a solid equilateral triangle symbol to focus only on resin identification, not on recyclability. Manual or automated sorting systems exist at an industrial scale separating plastics intended for recycling from other waste. Usually, presorting efficiently segregates glass, metal, and paper from the waste stream. Sorting of plastics might be supported by analytical techniques (e.g., near-infrared and Fourier-transform spectroscopy, optical color recognition systems) [1], although efficient separation remains a challenge due to different shapes of the plastics, entrapped air, coatings and paints that slow-down or even impede the analysis.

Mechanical recycling

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Mechanical recycling of plastics describes the conversion of thermoplastic polymers into products with equivalent properties [1, 4]. High quality food-contact grade recycled plastic can only come from closed-loop processes with plastics that have not been used at all (pre-consumer recycled) or which have been thoroughly cleaned and separated from contaminating plastics (i.e., not food contact grade) before recycling. Recycling of beverage bottles made of polyethylene terephthalate (PET) is the best-known example. In most cases, recycled PET is blended with 60% or more virgin material to achieve the needed material properties and chemical safety requirements. Fully or partially bio-based plastics that have the same material properties as conventional plastics can be recycled in existing recycling streams (e.g., bio-PET). However, wrong or incomplete sorting of biobased, biodegradable, or compostable materials may strongly disturb recycling and/or composting leading to products of low quality or even break-down of the processes [3].

Downcycling, or secondary recycling, generally leads to products of lower mechanical properties. Thermoplastics composed of only one polymer may be mechanically recycled after use, but a reduction of some polymer’s molecular weight and changes in physico-chemical properties often must be considered [4]. Plastic food packaging made from some resins such as polypropylene (PP) film or polystyrene (PS) cups when recycled are generally not turned back into food packaging.

Chemical recycling

Also known as advanced recycling or tertiary recycling, chemical recycling describes processes in which polymers are chemically or biologically degraded into smaller molecules that can serve as new building blocks for further chemical syntheses [1, 5]. Often, these processes have been found to have a high energy demand and generate toxic waste. The first series of chemical recycling pilot plants have also not yet been demonstrated to be economically viable to scale up and operate. More research is still needed to understand their impacts and if they could become a viable recycling option.

When plastics or plastic component molecules are used as fuel, it is sometimes called quaternary recycling, or advanced recovery, which creates energy from plastics through incineration. There is some evidence that facilities claiming they are undertaking chemical recycling are in fact making products that are ultimately burned, creating essentially a new form of fossil fuel based energy production [4].

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2. Recycled materials

Recycled polyethylene terephthalate (PET)

PET has become the most used packaging material for water and soft-drinks worldwide [6, 7]. Public concerns about environmental impacts of PET disposal, as well as the recyclability and availability of collected PET bottles promoted the development of PET recycling processes. In the beginning, PET recyclates were mainly used in the production of polyester fibers. Bottle-to-bottle recycling processes were then developed together with appropriate regulatory frameworks allowing the use of recycled PET in food contact materials (FCMs) [8, 9]. So-called “challenge tests” were established to measure whether a recycling process can reduce any chemical contamination below a set limit and thus comply with the legal requirements [10]. Contaminations might originate from PET containers previously filled with non-food liquids, from non-food-contact grade PET or from other types of polymers entering the recycling stream (Figure 1). Further PET degradation products, process chemicals, or sorbed food components can result in unwanted impurities.

A typical PET recycling process starts with the collection, separation, and sorting of post-consumer PET bottles in materials recovery facilities. In recycling facilities, post-consumer PET is washed to remove dirt, glue, and food leftovers and then ground into flakes. Additional cleaning steps necessary to obtain the purity required for food packaging include high temperature treatment, vacuum or inert gas treatment, and surface treatment with non-hazardous chemicals to achieve so-called super-clean PET [11].

Other materials

Besides PET, processes for the recycling of other packaging materials composed of, for example, polyolefins, multilayer materials, and (nano-)composites have been developed. Polyolefins are susceptible to oxidation, and it is still a challenge to maintain the material’s quality during a recycling process. However, additives and stabilizers may help to achieve recycled polyolefins of sufficient quality for reuse [12]. The recycling of plastic from multilayer materials is currently not economically feasible; instead, recycling only focuses on the fiber-based layers. The production of blends composed of plastic and fibers or nanomaterials is an alternative way to increase the stability of recycled plastic, but the further recyclability of these composite materials has not been routinely assessed so far.

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3. Market and recycling data

The prices for post-consumer resins increased over the last 25 years, but they were highly volatile [13]. In general, transparent recycled materials are more expensive than colored ones and pellets are more expensive than flakes. Currently, post-consumer HDPE is more expensive than PET. In 2012, 1’640, 779, 582 and of PET were collected for recycling in the EU, the U.S., Japan and Switzerland, respectively [14-16]. The recycling rates were the highest in Japan and Switzerland, followed by the EU and the US.

4. Regulations

European Union

In the EU, recycled plastic materials and articles intended to come into contact with foods were regulated under Commission Regulation (EC) No 282/2008, commonly referred to as the Recycling Regulation. Article 4 of the regulation specifies that all articles and plastic materials used for recycling must have been produced in accordance with Community legislation on plastic FCMs and articles. As of March 2022, 167 recycling processes, which can be found using the keyword RECYC, have been registered and partially evaluated by the European Food Safety Authority (EFSA), but none of the evaluated recycling processes has been authorized by the European Commission to this point. More than 80% of these processes describe the recycling of PET.

In March 2022, a revised draft of an updated recycled plastic FCM regulation was published (FPF reported).

United States

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In the US, the use of recycled plastic in the manufacturing of food contact articles is evaluated on a case-by-case basis by the US Food and Drug Administration (FDA). Between 1990 and 2021, 259 processes for producing post-consumer recycled plastic were judged suitable. Three-quarters of the registered processes specify the recycling of PET.

Japan

In 2000, Japan’s Container and Packaging Recycling Law came into full force with the aim to reduce the waste of glass, PET, paper and other forms packaging. At the time the law was drafted, containers and packaging accounted for 60% of waste by volume in Japanese households.

5. Safety issues

Contamination

The possible sources of contamination during recycling processes are diverse and often unknown (Figure 1). In different studies, phthalates, heavy metals, and brominated flame retardants have been identified in recycled plastics used as FCMs [18-21]. In some of these studies, unwanted contaminants were present, but the legal limits were not exceeded. When black plastic items used in food contact were found to be contaminated with brominated flame retardants, this was a surprise since they are generally not allowed to be used in FCMs [20]. They are hypothesized to have probably originated from waste electronics equipment that was fed (incorrectly) into the recycling stream.

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Environmental and health issues

Plastic recycling reduces the amount of plastic waste, but it can generate emissions that have an impact on the nearby environment. Studies have shown that especially in developing countries, occupational health and safety may not be sufficiently ensured in the plastic recycling industry [22]. This fact is of special concern due to the high amounts of plastic sent for recycling to these countries.

6. References

  1. Hopewell J, Dvorak R, and Kosior E. 2009. Plastics recycling: challenges and opportunities. Phil Trans R Soc B. 364:2115-26.
  2. Al-Salem SM, Lettieri P, and Baeyens J. 2009. Recycling and recovery routes of plastic solid waste (PSW): a review. Waste Manage. 29:2625-43.
  3. Geueke B, Groh K, Muncke JM. 2018. Food packaging in the circular economy: Overview of chemical safety aspects for commonly used materials. J. Cleaner Prod.
  4. NRDC. 2022. Recycling lies: “Chemical recycling” of plastic is just greenwashing incineration. [https://www.nrdc.org/sites/default/files/chemical-recycling-greenwashing-incineration-ib.pdf]
  5. Achilias DS, Roupakias C, Megalokonomos P, et al. 2007. Chemical recycling of plastic wastes made from polyethylene (LDPE and HDPE) and polypropylene (PP). J Hazard Mater. 149:536-42.
  6. Smithers Pira. 2014. Demand for PET Packaging Material to reach $60 billion by 2019. [https://www.smitherspira.com/news/2014/april/demand-for-pet-packaging-material-in-2019]
  7. George N, and Kurian T. 2014. Recent developments in the chemical recycling of postconsumer poly(ethylene terephthalate) waste. Ind End Chem. 53:14185-98.
  8. European Commission. 2014. 15th Update of the register of valid applications for authorisation of recycling processes to produce recycled plastic materials and articles intended to come into contact with foods submitted under article 13 of Regulation (EC) No 282/2008. [http://ec.europa.eu/food/food/chemicalsafety/foodcontact/docs/register_recycl_processes_art13_v14_en.pdf]
  9. FDA. 2014. Submissions on post-consumer recycled (PCR) plastics for food-contact articles. [http://www.accessdata.fda.gov/scripts/fdcc/?set=RecycledPlastics]
  10. Barthelemy E, Spyropoulos D, Milana MR, et al. 2014. Safety evaluation of mechanical recycling processes used to produce polyethylene terephthalate (PET) intended for food contact applications. Food Addit Contam A. 31:490-7.
  11. Welle F. 2011. Twenty years of PET bottle to bottle recycling – An overview. Resour Conserv Recy. 55:865-75.
  12. Xanthos M. 2012. Recycling of the #5 polymer. Science. 337:700-2.
  13. Plastic News. 2014. Current resin pricing – recycled plastics, November 3, 2014. [http://www.plasticsnews.com/resin/recycled-plastics/current-pricing]
  14. Council for PET bottle recycling. Recycling rate of PET bottle. [http://www.petbottle-rec.gr.jp/english/actual2.html]
  15. NAPCOR. 2013. Postconsumer PET container recycling activity in 2012. [http://www.napcor.com/pdf/NAPCOR_2012RateReport.pdf]
  16. PETCORE. 2013. More than 60 billion PET bottles recycled 2012! [http://www.petcore.org/news/more-60-billion-pet-bottles-recycled-2012]
  17. PET-Recycling Schweiz. 2017. PET-Recycling ist Umweltschutz. [http://www.petrecycling.ch/tl_files/content/PDF/Downloads%20PET-Recycling/2017_Broschuere_PET-Recycling_ist_Umweltschutz.pdf]
  18. Cheng X, Shi H, Adams CD, et al. 2010. Assessment of metal contaminations leaching out from recycling plastic bottles upon treatments. Environ Sci Pollut Res Int. 17:1323-30.
  19. Lee J, Pedersen AB, and Thomsen M. 2014. The influence of resource strategies on childhood phthalate exposure – The role of REACH in a zero waste society. Environ Int. 73:312-22.
  20. Samsonek J, and Puype F. 2013. Occurrence of brominated flame retardants in black thermo cups and selected kitchen utensils purchased on the European market. Food Addit Contam A. 30:1976-86.
  21. Whitt M, Vorst K, Brown W, et al. 2013. Survey of heavy metal contamination in recycled polyethylene terephthalate used for food packaging. J Plast Film Sheet. 29:163-73.
  22. Staffeld R, and Kulke E. 2011. Informal employment and health conditions in Dhaka’s plastic recycling and processing industry. In: Health in megacities and urban areas. A. Krämer, M.H. Khan and F. Kraas, eds. Springer Verlag, Berlin Heidelberg.

FAQs

What percentage of plastic packaging is effectively recycled? ›

Currently, only around 14% of plastic packaging is collected for recycling globally. Without fundamental redesign and innovation, about 30% of plastic packaging will never be reused or recycled. So while recycling is part of the solution, we won't recycle our way out of the plastic pollution crisis.

Why is achieving a 100% recycling rate for plastic packaging so difficult? ›

Consequently, there are thousands of variations of plastics. Not all types can be recycled. When the plastic that can be recycled is recycled, the quality degrades every time it is reheated for melting to make a new product.

How much of packaging is actually recycled? ›

Of the 40 million tons of plastic waste generated in the United States last year, only five to six percent—or about two million tons—was recycled, according to a new report, conducted by the environmental groups Beyond Plastics and The Last Beach Cleanup.

How much of the plastic waste is from packaging? ›

Approximately 36 per cent of all plastics produced are used in packaging, including single-use plastic products for food and beverage containers, approximately 85 per cent of which ends up in landfills or as unregulated waste.

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